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    • 专利摘要:
    Cold crucible furnace comprising: - a crucible for containing an electrically conductive material to be melted, the walls of electrically conductive material, and comprise a lateral envelope, cylindrical of revolution about an axis X and a sole provided with at least one plug, the lateral envelope and the sole being each divided into electrically insulated sectors, parallel to X; at least one lateral inductor with at least one turn wrapped around the lateral envelope; - At least one bottom inductor, at least one coil wound around X facing the underside of the sole leaving an area underneath the plug, - at least one magnetic flux concentrator consisting of a ferromagnetic part comprising at least one side wall and a bottom wall arranged facing the lower face and the outer periphery of the bottom inductor.
    公开号:FR3044748A1
    申请号:FR1561815
    申请日:2015-12-03
    公开日:2017-06-09
    发明作者:Guillaume Lecomte；Guy Willermoz；Patrice Brun
    申请人:Etudes Et Constructions Mec Tech；Commissariat a lEnergie Atomique CEA；Commissariat a lEnergie Atomique et aux Energies Alternatives CEA；
    IPC主号:
    专利说明:

    COLD HOLLOW OVEN HEATED BY TWO EUECTROMAGNETIC INDUCERS, USE OF THE OVEN FOR FUSION OF A MIXTURE OF METAL (UX) AND OXIDE (S) REPRESENTATIVE OF A
    CORIUM
    Technical area
    The present invention relates to a cold crucible furnace with electromagnetic induction heating, for melting at least one electrically conductive material, such as an oxide and / or a metal, comprising two inductors with at least one turn.
    The furnace according to the invention with a cold crucible may be a self-crucible furnace.
    A particularly interesting target application is the melting of a mixture of metal (ux) and oxide (s). A corium is a mixture of molten materials (UO2, ZrC> 2, Zr, steel) which, in cases of serious nuclear accidents, is likely to form during the fusion of nuclear fuel assemblies and nuclear control rods .
    Although described with reference to the fusion of a corium, the invention also applies to electromagnetic induction melting of any electrically conductive material. It is specified here that the fusion can quite be performed on an oxide which, although constituting a very good cold electrical insulator, is conductive beyond a certain temperature. Also, in the context of the invention, when the fusion of an oxide must be carried out, it is first initiated by means of a resistor, preferably in the form of a metal ring, usually called susceptor metal, around the furnace, and once the oxide has reached a certain temperature and is conductive, induction with the furnace according to the invention is possible in the oxide. The invention thus applies in particular to ovens used in foundry or metallurgy.
    State of the art
    In the field of foundry or metallurgy, the development of materials generally requires their melting and maintaining in their liquid state for a long enough time to obtain the homogenization of the liquid with respect to the various constituents or the temperature or to allow chemical reactions to be accomplished within the liquid. To do this, it is important that a stirring animates the liquid.
    Thus, in these fields, a widely used method for effecting the melting of large masses of metal is that of electromagnetic induction heating in a crucible furnace. The major advantages of such a process are its simplicity of implementation, its efficiency and the fact that it avoids any contact between the thermal energy source and the metal.
    FIG. 1 illustrates an induction heating furnace 1 comprising a crucible 2 intended to contain a charge 3, that is to say a certain mass and volume of an electrically conductive material. The lateral envelope of the crucible 2 is surrounded by an inductor 4 fed with alternating current at a certain high frequency, intended to heat by electromagnetic induction the charge 3 contained in the crucible.
    As illustrated in FIG. 1, the walls of the crucible are made of a refractory material, for example rammed earth or a conductive material, for example graphite. A disadvantage of these crucibles is that their walls rise to the temperature of the load. Thus, the refractory material constituting these walls (the container) and the impurities contained therein are capable of diffusing into the melt (the contents), which is particularly troublesome in the case where the crucibles are intended to contain materials. very reactive, for example alloys based on titanium or glasses / enamels, whose treatment is intended to provide a product of very high purity. This is also troublesome in the particular field of implementation which is that of the inventors: they have indeed been confronted with the need to achieve the fusion of a mixture of metal and oxides representative of a corium (UO2, Z1O2 , Zr, steel). However, not only the same problem of diffusion in the charge of the refractory material arises, but also the temperature to be reached for the corium fusion is of the order 3 000 ° K, the melting temperature of the U02 being this order of magnitude. No refractory material, except the thorium (TI1O2) whose supply is made impossible because of the radioactive nature of thorium (Th), is able to maintain this temperature.
    In addition, there are other disadvantages for the crucible. Firstly, the material of the molten charge can gradually penetrate into the container because of its porosity. The container dissolves little by little because of the strong reactivity of the molten material. The merger can not last long.
    The operating temperature of the walls of the crucible (container) is therefore in the conditions mentioned above, necessarily limited.
    Thus, the possible solution to achieve the melting of reactive materials with refractory materials and / or very high melting temperature is to use a crucible implementing the same principle of heating by electromagnetic induction but called cold crucible or cold walls . The self-crucible type induction furnace is also referred to in the literature as, at the inner periphery of the furnace, against the cold walls, a solidified layer of the material itself of the load is formed which may be considered as constituting the wall. internal crucible. Cold crucible furnaces have already proven themselves in small quantities, typically a few tens of kilograms of metal load.
    The reactive materials that can be melted at high temperature above 1500 ° C or even up to 3100 ° C in cold crucible furnaces can be both metallic, such as titanium, steel or various alloys, that oxides such as glass, titanium oxide, rare earth or a mixture thereof such as the corium mentioned above or even poorly conductive materials, such as silicon, enamels, glasses ...
    FIGS. 2 to 4 show a part of such a cold crucible furnace 1: the crucible 2 is formed by walls of electrically conductive material, divided vertically into several longitudinal sectors 20, hollow, electrically insulated from each other . These sectors 20 are commonly made of a metal such as copper which has the advantage of having a low electrical resistivity and of having good heat exchange qualities. These sectors are further internally traversed by a circulation of cooling fluid (not shown), commonly water. This cooling fluid makes it possible to maintain the internal surface of the sectors 20 in contact with the liquid charge at a temperature well below the melting temperature of the feedstock, typically below 300 ° C.
    According to the constraints of the melting process, the cold crucible 2 may comprise distinct sectors 20 between the lateral envelope 21, also called ferrule, and the bottom 22, also called sole, as illustrated in FIG. 2. In this configuration, the interface between the lateral envelope 21 and sole 22 is rather rectangular.
    Each sector 20 of the lateral envelope 21 and the sole 23 may also constitute a single sector 20 as illustrated in FIG. 3. In this configuration, it is possible to have sectors 20 whose inner wall between the envelope lateral 21 and the sole 22 has a hemispherical shape. The lateral envelope 21 of the cold crucible 2 is arranged inside an inductor 4 with at least one turn, supplied with alternating current I at a certain frequency which creates induced currents I in the sectors 20, currents I which close by traversing the inner wall of the crucible and in which they create a magnetic field. Thus, the high frequency current flowing in the inductor 4 produces a peripheral current in each of the sectors 20. The set of currents at the inner periphery of each sector 20 produces an electromagnetic field in the contained charge of the crucible. Indeed, any electrically conductive material in such a crucible is the seat of the induced currents that interact with the magnetic field created by the inductor 4 causes the appearance of electromotive forces called Lorentz forces. Thus, the currents induced in the load which correspond to the sum of the direct induction by the inductor 4 and the indirect induction by the cold crucible 2 make it possible to heat the material (s) of the charge up to at the fusion and the liquid charge is brewed because of the Lorentz forces but also the natural convection generated by the thermal gradients in the liquid charge.
    Because of the cooling circuit, the temperature of the inner surface of the sectors 20 is much lower than that of the melt load, and there is a rapid solidification of the molten material in contact with the sectors 20 of the crucible 2 and also with the sole 22, which creates a solid diffusion barrier layer avoiding reactivity between the sector material and the melt material. In other words, there is creation of a thin crust, by solidification of the load over a few millimeters or centimeters that is called in the state of the art self-crucible load or cold crucible. This cold crucible admits a thermal gradient of a temperature of the order of 20 ° C to 250 ° C with the cold copper crucible to the solidus temperature of the molten charge.
    Thus, cold crucible furnaces have all the advantages of "hot" induction furnace induction furnaces mentioned above, such as the use at high temperatures, with further high purity of the load due to the absence of pollution by the crucible, making a stirring which makes the composition of the molten liquid charge uniform and improves heat transfer and therefore increases the temperature homogeneity.
    On the other hand, the known cold crucible furnaces present, by their operating principle, several constraints.
    As mentioned above, the lateral inductor 4 which heats the charge of material to be melted injects power by Joule effect in the material which is at a certain thickness at the periphery of the load, the value of which varies as a function of the frequency of the supply current of the inductor and the resistivity of the charge of the material to be melted. The lower part of the crucible being of electrically conductive material, such as copper, it modifies the magnetic field lines and thus the induced currents. Thus, the Joule effect power injected is less strong in the lower part of the crucible, as illustrated in FIG. 5 where it is clearly seen that the distribution Σ of induced power density decreases linearly, rapidly as the we are getting closer to the sole 22.
    This phenomenon combined with the cooling of the sectors 20 of the lateral envelope 21 and the hearth 22 leads to a crustal thickness which is greater on the hearth 22 than on the lateral envelope 21, as shown in FIG. 6. crust thickness e1 on the hearth 22 may be from 2 to 3 times more or even up to 10 times the thickness e2 on the lateral envelope 21 according to the configuration of the lateral inductor 4 and the cooling retained. FIG. 6 clearly distinguishes the crust formed with its two thicknesses e1, e2 which contains the liquid bath B for melting the material or materials with a transition zone T between them. Thus, the liquid bath B is in the upper part and this despite the thermo-hydraulic phenomena reinforced by the Lorentz forces generated by the lateral inductor 4.
    The crust thicknesses vary according to the type of material (x) that is to be melted. The lower the thermal conductivity, the greater the thickness of the crust. It is specified here that for transparent materials such as glass, it is necessary to consider an apparent thermal conductivity with a part due to the conduction and a part due to radiation. For metals for which the thermal conductivity is rather high, typically of the order of 10 to 50 watts per meter-Kelvin (W m -1 K 1), the thickness of the crust may be of the order of 1 mm. for oxides and / or for materials of low thermal conductivity, typically of the order of 1 to 5 W-m_1-K "*, the thickness can reach several tens of mm.
    Once the (s) material (s) melted (s), the casting thereof (these) in the liquid state by melting can then be performed. On this point, it is important to take into account the fact that the greater the mass of the self-crucible that can not be cast, is important plus the material yield of the melting process is reduced.
    Two casting modes can be envisaged: either by tilting of the crucible or by gravity by removing a plug 23 housed in the hearth 22.
    In many applications, crucible failover mode can not be retained for technological and cost reasons. In particular, in the field of implementation faced by the inventors, the melting of a mixture of materials representative of a corium requires placing in a controlled atmosphere. Consider switching a cold crucible furnace under such a chamber would involve the dimensioning of a very large enclosure. In addition, because the furnace includes cooling circuits that are physically present on its entire periphery, a switchover would require taking very complex measurements. Finally, the time dedicated to the changeover can be very restrictive.
    Gravity casting also has a number of constraints. First, once cap removed, in order to clear a through opening through which the liquid bath of material or the mixture of materials will be able to flow, it is necessary to break the crust in the bottom of the crucible. This is done by a mechanical element of striker type.
    However, the greater the thickness of the crust, the more difficult it is to break even impossible without damaging the integrity of the crust and / or equipment around.
    Also, to achieve conventional casting involves overheating the molten liquid bath. However, the thermal losses are important because there are both radiation losses on the surface of the bath, losses by conduction on the walls of the crucible and convective losses according to the surrounding atmosphere. These losses induce a general process yield which can be very low of the order of 10%. And, in the case of supercooling, the losses are further increased by a factor of 1.5 to 2 times depending on the supercooling temperature, which further impacts the efficiency of the process. To compensate for this, the electric power of the induction generator is conventionally increased and the cooling system is further dimensioned. The overall equipment is therefore oversized only for casting, with an additional cost. Even taking these steps, it is not certain that the supercooling is sufficient to ensure casting.
    One solution that has already been considered is to add an inductor locally around the casting area below the sole, which is the plug location area and intended to be cleared by the withdrawal of the latter. FIG. 7 diagrammatically shows such an inductor, called casting 4 ', as it is arranged around the transfer zone 24 of the casting. This casting inducer 4 'makes it possible to create additional induced currents around the zone of the liquid bath Zb in line with the casting zone 24 and thus to heat this zone Zb, thereby weakening the crust at this level. FIG. 8 schematizes the power density distributions ΣΙ, Σ2 induced respectively by the lateral inductor 4 and the inductor 4 '.
    This solution with a casting inductor is for example described in publications [1] to [7] or even in patent EP1045216B1. This solution only concerns the melting of metal, such as that of titanium scrap according to this patent, at a temperature of at most 1700 ° C. and can not therefore be suitable in a problem of melting oxides.
    Some melting processes require crucibles whose diameter is much greater than their height. It is then necessary to arrange the inductor below the sole. Such an inductor, said bottom 5 is shown schematically in Figure 9, where we also see the power density distribution Σ3 it generates. In this configuration, the convection thermal losses can be significant because directly related to the free surface of the liquid bath and conductive heat losses on the wall of the lateral envelope are not compensated due to the absence of lateral inductor .
    In summary, the disadvantages of conventional cold crucible furnaces are related to a thickness of crust which is (too) important in the direction orthogonal to the location of the inductor, in general on the bottom (sole) because of the arrangement of a lateral inductor in most cases. This large thickness makes it necessary to overheat the liquid bath in order to locally reduce the crust, which has the major drawbacks of increasing the heat losses and requiring oversizing of the power of the induction generator and the cooling circuit of the furnace. .
    One solution that has already been considered, as described in the publication [8], consists in adding a lateral turn very far away from the turns positioned below the hearth and ultimately forming a single inductor with the inductor of the bottom. This lateral turn injects a localized power in the upper part of the bath. This solution is not suitable for the total melting (lateral and bottom) of materials as considered in the main application referred to in the context of the invention.
    Another solution is to arrange two inductors, that is to say to add in addition to the lateral inductor, an inductor, said bottom, below the sole but leaving unobstructed the casting area.
    It is thus possible to obtain a continuity of the power density in the material (s) to be melted, which makes it possible to reduce the thickness of the crust in the bottom, ie in contact with the sole, and without it is necessary to overheat the liquid bath as in the conventional solutions mentioned above. Without overheating to achieve supercooling, heat losses are not significantly increased and the induction power can be better optimized.
    US Pat. No. 4,609,425 describes such a solution with a cold crucible furnace with two separate inductors, one of which is a lateral and a bottom. The melting temperature that can be achieved with the described furnace is limited to about 1550 ° C, which rules out any fusion with oxides. In addition, the temperature resistance and the implementation of the dielectric material of the furnace hearth is delicate and can not be suitable for fusions of the order of 2200 ° C and preferably 3000 ° C.
    US Patent 4687646 also discloses a cold crucible furnace with a side inductor and a bottom inductor. This patent certainly mentions fusion of oxides but the disclosed oven can not actually achieve the melting of a mixed mixture of oxides / metal, has the same disadvantages as the oven according to US Patent 4609425 and in addition, because of its configuration, prohibits gravity casting.
    JP 10253260 also discloses a cold crucible furnace with two separate inductors which only allows the melting of metals, with very low induction frequencies of the order of 60 Hz and lower melting temperatures than those of the oxides. The authors of this patent seek to avoid at all costs the formation of a crust and therefore dedicate the bottom inductor to lift the melt so that it does not come into contact with the sole. The support of the bottom inductor and the sole according to this patent are shaped to define a cooling water circuit of the bottom inductor. Therefore, the sole must be waterproof and its walls are necessarily continuous, that is to say, it is not divided into sectors. Also, if one sought to operate the proposed bottom inductor at higher induction frequencies, it is very likely that the induced currents could cross the sole or at least enough to create a satisfactory fusion. More precisely, to obtain an oxide melting, the induction frequency must be a few hundred kHz or even 100 kHz. Lorentz's forces are quite weak. Therefore, if one seeks to obtain a high melting temperature, a dielectric material of the hearth can not be suitable. On the other hand, if the sole according to this patent JP 10253260 is metallic, since it is not sectorized, the magnetic field induced at a high frequency, of the order of 100 kHz, could not cross the sole and therefore could not develop currents induced in the charge to melt.
    In addition to the aforementioned drawbacks of US Pat. No. 4,6094,252, US Pat. No. 4,681,746 and JP 10253260, the disclosed solutions with two separate inductors, one lateral and one bottom, have a major disadvantage. Each of the two inductors can induce currents in surrounding rooms. In particular, and especially the current induced by one of the inductors disturbs the other inductor and vice versa, a phenomenon that is usually referred to as "mutual". In addition to the fact that the efficiency of the disturbed inductor is reduced, particularly that of the bottom, this presents the risk that the disturbances are unacceptable for two independent current generators with potentially different operating frequencies, the control electronics of which can not not support the induced currents in return. In the case of a single current generator for the two inductors combined with a power distribution system on the two inductors, the operating frequency is identical. Mutuals can then only come down the yield and not have an optimized power density distribution.
    There is therefore a need to improve cold crucible furnaces with electromagnetic induction heating, in particular with a view to enabling a reduction in the thickness of the crust on the hearth without generating a supercooling of the liquid bath of the material or materials thereof. melting, in particular which contains oxides, and / or without appreciably increasing the cost of furnace equipment, and / or without generating harmful induced currents likely to disturb the surrounding parts of the inductor (s), especially the current generators.
    The object of the invention is to respond at least in part to this need.
    Presentation of the invention
    To this end, the invention has, in one of its aspects, a cold crucible furnace, heated by electromagnetic induction, intended to melt at least one electrically conductive material, such as an oxide and / or a metal, comprising: - a crucible for containing the material to be melted, whose walls are made of electrically conductive material, preferably copper, and comprise a generally cylindrical lateral envelope of revolution about an axis X and a bottom called sole, provided with at least one plug, the lateral envelope and the sole being each divided into electrically isolated sectors, which extend parallel to the axis X; at least one inductor, said lateral inductor with at least one turn, wound around the outer periphery of the lateral envelope; - At least one inductor, said bottom inductor, at least one turn wrapped around the X axis facing the underside of the sole leaving a clear area below the cap.
    The two inductors, i.e. the lateral one and the bottom one, are used for melting and homogenizing the charge to be melted.
    According to the invention, the furnace furthermore comprises at least one magnetic fluxconcentrator device consisting of a piece of ferromagnetic material comprising at least one sidewall and a bottom wall respectively arranged facing the lower face and the outer periphery. of the bottom inductor.
    By "magnetic flux concentrator" is meant here and in the context of the invention, a piece of relatively high or very high relative magnetic permeability material, that is to say with a prbien value greater than 1. It can advantageously be a ferrite part or a part consisting of a stack of magnetic sheets.
    It is specified that the concentrator part according to the invention has a general shape of revolution about the X axis which may comprise one or more indentations, openings, grooves for passing, if appropriate, the electrical current leads of the inductor of the which may further include the coolant coolant supply pipes of the bottom inductor. The invention therefore consists in surrounding the major part of the bottom inductor which is not directly facing the sole, by an element whose high or very high magnetic permeability will make it possible to confine the magnetic fields generated by the bottom inductor, in an area at the bottom of the crucible in contact with the hearth.
    Thus, by confining or otherwise by locating the magnetic fields, their action on the material charge (x) to be melted will be improved. Thus, the efficiency of the bottom inductor is increased without any need to oversize the equipment of the cold crucible furnace. The inventors believe that it is possible to increase the efficiency up to a factor of 20 to 30% compared to a solution with two inductors without the concentrator according to the invention.
    In addition, the concentrator according to the invention makes it possible to avoid or at least greatly reduce the occurrence of mutuals between the lateral inductor and the bottom inductor. This avoids the risk of electromagnetic disturbance of the induction generators and thus makes it easier to have two different power supplies with dedicated frequencies, one for the lateral inductor and the other for the inductor.
    Finally, the concentrator according to the invention makes it possible to increase the Lorentz forces inside the material (s) to be melted. Thus, thanks to the concentrator according to the invention in configurations with the presence of metal in the filler to be melted, in which the thermal losses by conduction are greater than in the presence of oxides, conditions of semi-levitation of the load can be reinforced and thus reduce thermal losses by contact. The frequencies in these configurations will be preferentially lower.
    The magnetic concentrator solution according to the invention is different from an EM shielding screen that could be recommended by a man of the state of the art: indeed, faced with the problem of occurrence of mutuals between lateral inductor and bottom inductor , it would rather tend to achieve as conventionally an electromagnetic shielding screen between the two inductors but not only such a screen might induce other currents detrimental to the desired fusion goal but also certainly could not effectively confine the magnetic field of the inductor. It must also be emphasized that under no circumstances can an electromagnetic shielding screen be assimilated to a magnetic flux concentrator according to the invention.
    According to an advantageous embodiment, the part of the magnetic flux concentrator further comprises a lateral wall arranged facing the inner periphery of the bottom inductor, the two side walls and the bottom wall of the part defining substantially a shape. U in which is arranged the bottom inductor. With this additional side wall, it is avoided to raise all the currents that could be induced by a conductive wall for casting the (the) material (s) melt.
    According to another advantageous embodiment, it may be provided to arrange an additional magnetic concentration ring, segmented or not, below the lateral inductor. As a result of calculations made by the inventors, in certain geometric configurations of proximity of the two inductors and of high potential powers, the inventors have been able to observe that the presence of the additional ring of magnetic concentration advantageously makes it possible to greatly reduce mutuals between two inductors.
    Such an additional magnetic concentrator below the lateral inductor makes it possible to reinforce the results of the magnetic concentrator described above. Indeed, depending on the power, the frequencies and the proximity of the two inductors, this additional magnetic concentrator element (ring or segment) increases the efficiency of the inductor and reduces the mutual to make them almost nonexistent.
    Preferably, the concentrator part according to the invention is made of ferrite or made from magnetic sheets.
    According to an advantageous variant, the lateral inductor and the bottom inductor are able to operate simultaneously at different frequencies.
    According to this variant, it may be advantageous for the operating frequency of the base inductor to be slightly lower than that of the lateral inductor.
    In the case of oxides and mixed oxide / metal materials to be melted, for load capacities the order of 30kg to 1000kg: - the power sources of the lateral inductor and the bottom inductor are dimensioned to operate in the frequency range of about 500 Hz to 300 kHz depending on the filler to be melted; in the specific application of corium fusion, the power sources of the lateral inductor and the bottom inductor are preferably sized to operate over the frequency range of about 80 kHz to 160 kHz.
    In general, it is possible to choose an operating frequency of the lateral inductor or of the base inductor which is suitable for the melting of one or more metals (ux) and the other of the operating frequencies of the inductor lateral or bottom inductor being adapted for melting one or more oxide (s). The invention also relates, in another of its aspects, the use of the oven described above for melting a mixture of at least one or more metals with one or more oxides.
    The mixture can be a mixture of metals (steel, zirconium, ...) with oxides (uranium UO2, zirconium, ...) as well as concrete components, the mixture being representative of a corium.
    DETAILED DESCRIPTION Other advantages and features will become more apparent upon reading the detailed description, given by way of nonlimiting illustration, with reference to the following figures, in which: FIG. 1 is a partially cut away perspective view of a furnace; crucible with electromagnetic induction heating; FIG. 2 is a partially cutaway perspective view of an exemplary embodiment of a crucible for a cold crucible furnace with electromagnetic induction heating, in which the lateral envelope and the hearth are each divided into identical sectors with the sectors of the lateral envelope being different from those of the sole; FIG. 3 is a partially cutaway perspective view of another embodiment of a crucible for a cold crucible furnace with electromagnetic induction heating, in which the lateral envelope and the hearth are each divided into identical sectors with each common sector. at the same time to the lateral envelope and to the sole the sole; - Figure 4 is a schematic top view of a crucible furnace also electromagnetic induction heating forming a cold crucible furnace; FIG. 5 is a schematic longitudinal half-sectional view of an induction-heated cold crucible furnace with only one lateral inductor according to the state of the art, FIG. 5 showing the power density distribution along the wall of the lateral envelope; - Figure 6 shows Figure 5 and shows the liquid bath of material (x) melt in the crucible and the thickness of the crust on the side shell and on the sole; FIG. 7 is a schematic longitudinal half-sectional view of an induction-heated cold crucible furnace with a lateral inductor and a casting inductor according to the state of the art, FIG. 7 showing the liquid bath of material (s) melted in the crucible and the local melting zone above the plug, the thicknesses of the self-crucible crust on the lateral envelope and on the hearth; FIG. 8 shows FIG. 7 and shows the power density distribution along the wall of the lateral envelope and above the plug; FIG. 9 is a schematic longitudinal half-sectional view of an induction-heated cold crucible furnace with a crucible with a diameter greater than its height and a single bottom inductor according to the state of the art, FIG. 9 showing the power density distribution along the wall of the hearth; FIG. 10 is a schematic longitudinal half-sectional view of an induction heating cold crucible furnace with a lateral inductor, a base inductor and a magnetic flux concentrator according to the invention, FIG. power density both along the wall of the side casing and the hearth for identical operating frequencies between inductors; - Figure 11 shows Figure 10 and shows the liquid bath of material (x) melt in the crucible and the thickness of the self-crucible crust on the side shell and on the sole; FIG. 12 shows FIG. 10 and showing the power density distribution both along the wall of the lateral envelope and the hearth for an operating frequency of the lower inductor than that of the lateral inductor; FIG. 13 is a schematic longitudinal half-sectional view of an induction heating cold crucible furnace with a lateral inductor, a base inductor and a magnetic flux concentrator according to the invention, to which is added a magnetic flux concentrator; additional below the lateral inductor; - Figure 14 is a view similar to Figure 13 showing an alternative embodiment of the additional magnetic flux concentrator according to the invention.
    Throughout the present application, the terms "vertical", "lower", "upper", "lower", "high", "below" and "above", "inside", "outside" are to be understood by reference to an induction heating cold crucible furnace arranged in a vertical operating configuration. Thus, in an operating configuration, the furnace is arranged vertically with its bottom (sole) through which the molten material is discharged, downwards.
    Figures 1 to 9 have already been commented on in the preamble. They are therefore not described in detail below.
    For the sake of clarity, the elements common to a cold crucible furnace according to the state of the art and according to the invention are designated by the same reference numerals.
    FIG. 10 shows a cold crucible furnace 1 comprising at least one magnetic flux concentrator 6 according to the invention. Such a furnace 1 is preferably intended to effect the melting of a charge consisting of a mixture of metal (ux) and oxide (s), such as uranium oxide UO2, representative of a corium.
    Such an oven 1 comprises a copper crucible 2 surrounded by a lateral inductor, i.e. an electromagnetic induction coil 4 with at least one turn wound around the outer periphery of the lateral envelope 21 of the crucible. In the example shown, the inductor 4 comprises a number equal to four consecutive turns 40-43 identical and equidistant from each other.
    Although not shown, the side wall of the crucible 2 is divided into a number of identical sectors.
    The crucible 2 also comprises a bottom 22, called sole. The bottom 22 comprises a plug 23 to allow the evacuation of the material or mixture of materials once it (these) in the liquid state by melting.
    By thus dividing the wall or lateral envelope 21 of the crucible 2 into sectors 20, when the alternating current flows through the coil or turns of the inductor 4, the induced currents do not remain localized at the periphery of the crucible, but go around each sector 20, as already explained in the preamble in relation to FIG. 4. The set of currents at the inner periphery of each sector 20 produces an electromagnetic field in the charge contained in the crucible.
    Thus, the currents induced in the load which correspond to the sum of the direct induction by the inductor 4 and the indirect induction by the cold crucible 2 make it possible to heat the material (s) of the charge up to at the fusion and the liquid charge is brewed because of the Lorentz forces but also the natural convection generated by the thermal gradients in the liquid charge. When the molten charge has become liquid, it comes into contact with the walls of the crucible 2 cooled by the not shown cooling circuit, which solidifies it, thus creating a crust, that is to say a solid layer made in the material (s) of the charge initially introduced into the crucible 2. The use of such a furnace 1 with a cold crucible is advantageous for the melting of a charge constituted by a mixture of uranium oxide and metal representative of a corium. Indeed, the melting temperature of the uranium oxide is of the order of 2865 ° C, well above the melting temperature of metals, especially titanium. The metal at these temperatures is characterized by a viscosity almost zero, that is to say, it can infiltrate into the slightest crack of the crucible.
    With the formation of the crust as explained above, it is ensured on the one hand that the metal present in the filler to be melted can in no case attack the metal constituting the walls of the crucible and secondly that the mixture of materials retains its initial purity.
    Preferably, an element, not shown in electrical insulating material is arranged between two consecutive sectors (adjacent). An insulating element tel serves not only to prevent leakage and decrease heat losses, but also, to minimize the arcing between the copper sectors 20 during operation of the furnace.
    As illustrated in FIG. 10, the furnace 1 also comprises a bottom inductor 5 with at least one turn 50, 51, 52 wound around the axis X facing the lower face of the hearth 22 leaving a clear zone below the plug 23. In the illustrated example, the bottom inductor 5 has three identical and equidistant turns of each other.
    Having as heating means, both a lateral inductor 4 and a bottom inductor 5 provides a continuity of the power density induced in the material of the filler to melt. Thus the crust thickness can be better distributed, without there being any need for supercooling the load as in conventional solutions according to the state of the art. As a result, the heat losses are not increased significantly and the induction power can be optimized.
    That said, the inventors have analyzed that the current induced by the base inductor 5 is likely to disrupt the operation of the lateral inductor 4, and vice versa. This phenomenon known as the "mutuals" can go as far as damaging the induction generators bottom is lower.
    Also, the inventors have implanted a magnetic flux concentrator 6 consisting of a piece 60 of ferromagnetic material comprising at least one side wall 61 and a bottom wall 62 respectively arranged facing the lower face and the outer periphery of the inductor 5.
    The piece 60 made of ferromagnetic material thus makes it possible to confine the magnetic field created by the bottom inductor 5 in the local area on the floor 22 around the central plug 23.
    This not only reduces or even eliminates any mutual but also increases the performance of the inductor 5. This is illustrated by Figure 10 where we see that there is a good distribution Σ of the induction power density both on the lateral envelope 21 and on the hearth 22.
    FIG. 11 illustrates the homogeneous bath B of molten material (x) and the quasi-uniform thickness distribution e of the crust obtained thanks to the two inductors 4, 5 with the magnetic flux concentrator according to the invention.
    According to an advantageous embodiment, when the filler to be melted consists of a mixture of oxides and at least one metal, such as a representative mixture of a corium, is circulated in the lateral inductor 4 an alternating current operating at a frequency different from that of the base inductor 5. In fact, the temperature of the metal, such as titanium typically around 1800 ° C, is significantly lower than that of the oxides, such as UO2 uranium oxide at about 2865 ° C.
    Thus, by supplying the lateral and bottom inductors 5 at one of two frequencies, one of which is suitable for the induction melting of the metal (of the metals) and the other of the oxides, it is ensured that simultaneous melting of the constituents of the mixture while ensuring a mixing and therefore a homogeneous mixture, and in addition, it is ensured that, throughout the melting process, the metal (metals) does not come into direct contact with the walls of the crucible. Indeed, on the one hand, for the same material, the higher the induction frequency, the more the electromagnetic wave will penetrate the material and thus generate Joule heating in the mass. On the other hand, as said before, because of their difference in melting temperature, oxides require higher induction frequencies and the metal (metals) lower frequencies.
    Finally, once the melting process in the oven has been initiated, the metal (metals) has (have) a near-zero viscosity when the oxides begin to melt.
    Thus, by using a single induction frequency for the operation of an oven according to the invention, there remains a risk that the molten metal (metals) seeps into the slightest crack in the walls of the crucible. . There is also a risk that the metal (metals) come (s) to stick somehow on said walls, which would have the detrimental effect of producing a screen electromagnetic waves and possibly deteriorate the cold crucible.
    Consequently, the operation of an oven according to the invention at two different frequencies, one for the lateral inductor 4, the other for the bottom inductor 5, makes it possible to avoid at least reducing these risks. : throughout the melting process, the metal (metals) is (are) repulsed towards the inside of the crucible. This gives a homogeneous mixture in a system of equilibrium of the melt components. This being so, especially in the case where the charge to be melted consists mainly of oxide (s), the lateral inductor 4 and the bottom inductor 5 can operate at relatively similar frequencies, or even identical.
    FIG. 12 illustrates this advantageous embodiment with an operating frequency of the bottom inductor 5 which is lower than that of the lateral inductor 4: the power density distribution Σι is therefore less important on the envelope 21 only on the floor 22.
    FIGS. 13 and 14 show an advantageous embodiment of a furnace according to the invention. According to this mode, it is intended to arrange an additional magnetic concentration element in the form of a ring 7, segmented or not, below the lateral inductor 4.
    As illustrated, this ring 7 may comprise a single wall 70 which extends orthogonally to the turns 40, 41, 42, 43 of the lateral inductor 4 (FIG. 13), or it may comprise an additional wall 71 which extends parallel to the turns 40, 41, 42, 43 of the lateral inductor 4 (Figure 14).
    This ring 7 below the lateral inductor 4 reinforces the results of the magnetic concentrator 6, 60. Indeed, according to the power, the frequencies and the proximity of the two inductors 4, 5, the ring 7 increases the efficiency of the inductor 5 and reduce the mutuals to make them almost nonexistent.
    Preferably, the power sources of the side inductor 4 and the base inductor 5 are sized to operate over the frequency range of about 500 Hz to 300 kHz depending on the filler to be melted.
    More preferably, in the specific application of corium fusion, the power sources of the lateral inductor 4 and the bottom inductor 5 are preferably sized to operate over the frequency range of about 80 kHz to 160 kHz. The invention is not limited to the examples which have just been described; it is possible in particular to combine with one another characteristics of the illustrated examples within non-illustrated variants.
    REFERENCES CITED
    [1]: J. Reboux "High frequency induction currents and their use in the high temperature ofveryfield" He Ed. "Steel". -France. - 1965.
    [2]: Petrov Yu.B., & Vasilyev A.S. (1966) Avtorskoe svidetel'stvo Ml85492 and 05.11.1965. Byulleten 'izobretenij, 17, 70. (in Russian) [3]: Petrov YU.B., Beshta S.V., Lopukh D.B. and el. (1992) "Fizicheskoe modelirovanie tyazhelykh avarij korpusnykh reaktorov i issledovanie zhidkogo koriuma sispol'zovaniem induktsionnoj plavki v kholodnom tigle" ("Physical modeling of severe accidents of reactor vessels and research ofliquid corium using induction melting in a cold crucible"). 3rd International Conference of Nuclear Society in the USSR, Sankt-Peterburg (in Russian) [4]: Bechta S., Khabensky V., Vitol S., Krushinov E., Lopukh D., Petrov Y., Petchenkov A., Kulagin I., Gra-Novsky V., Kovtunova S., Martinov V., Gusarov V. (2001) "Experimental studies of oxidic molten corium-vessel Steel interacting", Nuclear Engineering and Design, 210 (13): 193-224 , 2001. ISSN 0029-5493 http://www.sciencedirect.com/science/article/pii/S0029549301003776.
    [5]: Asmolov V.G., Bechta S.V., Khabensky V.B. et al. 2004. "Partitioning of U, Zr and Fe between molten oxidic and metallic corium", Proceedings of MASCA Seminar 2004, Aix-en-Provence, France.
    [6]: S.V. Bechta, V.B. Khabensky, V. S. Granovsky et al. CORPHAD and METCOR ISTC projects. The first European Review Meeting on Severe Accident Research (ERMSAR2005), SARNET FI60-CT-2004-509065, Aix-en-Provence, France, 14-16 November 2005, Session 2: CORIUM TOPICS, NI.
    [7]: S. HONG, B. MIN, J. SONG and H. KIM: "Application of cold crucible for melting of U02 / Zr02 mixture". Materials Science and Engineering: A, 357 (12): 297-303, 2003. ISSN 0921-5093. http://www.sciencedirect.com/science/article/pii/S092150930300248X: [8]: DBLopuch, AP Martinov, AV Vavilov, PM Garifullin "Experimental research of the conditions of passive drainage from the bottom of the glass melt by induction melting in a cold crucible ", 67th scientific and technical conference Faculty of the University Section of electrical engineering and electrical conversion, Acts of students, graduate students and young scientists 157-160 pp (in Russian)
    权利要求:
    Claims (11)
    [1" id="c-fr-0001]
    An electromagnetic induction heated furnace (1) for melting at least one electrically conductive material, such as an oxide and / or a metal, comprising: - a crucible for containing the material to be melted , whose walls (20) are made of electrically conductive material, preferably of copper, and comprise a side shell (21) of generally cylindrical shape of revolution about an axis X and a bottom, called sole (22), provided with at least one plug (23), the lateral envelope (21) and the sole (22) being each divided into electrically isolated sectors, which extend parallel to the X axis; - At least one inductor, said lateral inductor (4) to at least one turn (40, 41, 42, 43), wound around the outer periphery of the lateral envelope; at least one inductor, said bottom inductor (5), with at least one turn (50, 51, 52) wound around the axis X facing the lower face of the hearth leaving a zone underneath the plug (23), characterized in that it further comprises at least one magnetic flux concentrator device (6) consisting of a ferromagnetic material part (60) comprising at least one side wall (61) and a wall of the bottom (62) respectively arranged facing the lower face and the outer periphery of the bottom inductor (5).
    [2" id="c-fr-0002]
    2. Furnace with cold crucible according to claim 1, the workpiece of the magnetic flux concentrator further comprising a side wall (63) arranged facing the inner periphery of the bottom inductor (5), the two side walls (61). 63) and the bottom wall (62) of the workpiece defining substantially a U-shape in which the bottom inductor (5) is arranged.
    [3" id="c-fr-0003]
    3. Furnace cold furnace according to claim 1 or 2, comprising a ring (7, 70, 71) of additional magnetic concentration, segmented or not, below the lateral inductor.
    [4" id="c-fr-0004]
    Cold furnace according to one of the preceding claims, the part being made of ferrite or made from magnetic sheets.
    [5" id="c-fr-0005]
    Cold furnace according to one of the preceding claims, the lateral inductor (4) and the bottom inductor (5) being able to operate simultaneously at different frequencies.
    [6" id="c-fr-0006]
    6. Cold furnace furnace according to claim 5, the operating frequency of the bottom inductor being lower than that of the lateral inductor.
    [7" id="c-fr-0007]
    7. Furnace with cold crucible according to one of the preceding claims, the operating frequency of the lateral inductor and the bottom inductor being between about 500Hz and 300kHz
    [8" id="c-fr-0008]
    8. Furnace cold furnace according to one of claims 7, in the case of a representative mixture of a corium to be melted, the operating frequency of the side inductor and the inductor bottom is between 80kHz and 160kHz
    [9" id="c-fr-0009]
    9. Cold crucible furnace according to one of claims 5 to 8, one of the operating frequencies of the lateral inductor (4) or the bottom inductor (5) being adapted for melting one or several metals (ux) and the other operating frequencies of the lateral inductor (4) or the bottom inductor (5) being adapted for melting one or more oxide (s).
    [10" id="c-fr-0010]
    10. Use of the oven according to one of claims 1 to 9 for the melting of a mixture of at least one or more metals with one or more oxides.
    [11" id="c-fr-0011]
    11. Use according to claim 10, the mixture being a mixture of metals (steel, zirconium, ...) with oxides (uranium UO2, zirconium, ...) and components of the concrete, the mixture being representative of a corium.
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    同族专利:
    公开号 | 公开日
    RU2018120241A3|2020-01-09|
    RU2717123C2|2020-03-18|
    CN108603723B|2021-04-13|
    KR20180087326A|2018-08-01|
    KR102047614B1|2019-11-21|
    RU2018120241A|2020-01-09|
    CN108603723A|2018-09-28|
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    JP2019505753A|2019-02-28|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    WO2006127792A2|2005-05-26|2006-11-30|Crucible Materials Corporation|Cold wall induction nozzle for induction melting apparatus|
    US20120236898A1|2011-03-14|2012-09-20|Keough Graham A|Open Bottom Electric Induction Cold Crucible for Use in Electromagnetic Casting of Ingots|
    WO2014174489A1|2013-04-26|2014-10-30|Commissariat A L'energie Atomique Et Aux Energies Alternatives|Electromagnetic induction furnace and use of the furnace for melting a mixture of metal and oxide, said mixture representing a corium|
    DE3316546C1|1983-05-06|1984-04-26|Philips Patentverwaltung Gmbh, 2000 Hamburg|Cold crucible for melting and crystallizing non-metallic inorganic compounds|
    DE3316547C2|1983-05-06|1985-05-30|Philips Patentverwaltung Gmbh, 2000 Hamburg|Cold crucible for melting non-metallic inorganic compounds|
    NO890076D0|1989-01-09|1989-01-09|Sinvent As|AIR CONDITIONING.|
    DE4320766C2|1993-06-23|2002-06-27|Ald Vacuum Techn Ag|Device for melting a solid layer of electrically conductive material|
    JPH10253260A|1997-03-10|1998-09-25|Shinko Electric Co Ltd|Soft contact type cold crucible melting pot|
    JP2000088467A|1998-09-18|2000-03-31|Fuji Electric Co Ltd|Floating melting apparatus|
    US6144690A|1999-03-18|2000-11-07|Kabushiki Kaishi Kobe Seiko Sho|Melting method using cold crucible induction melting apparatus|
    AU2002257311B2|2001-05-22|2006-11-30|Inductotherm Corp.|Furnace with bottom induction coil|
    RU109281U1|2011-04-18|2011-10-10|Открытое акционерное общество "Технологии экокультуры" |Induction Crucible Furnace|FR3072768B1|2017-10-25|2020-01-24|Roctool|METHOD AND DEVICE FOR MOLDING IN PARTICULAR A METAL GLASS|
    FR3092655B1|2019-02-07|2021-02-12|Inst Polytechnique Grenoble|Cold crucible|
    FR3100421B1|2019-08-30|2021-09-10|Commissariat Energie Atomique|Induction furnace including an additional resonant circuit|
    CN111811275B|2020-06-24|2021-10-08|中国科学院金属研究所|Method for melting and melting high-melting-point mixture by utilizing sandwich material distribution mode and electromagnetic induction|
    法律状态:
    2016-12-30| PLFP| Fee payment|Year of fee payment: 2 |
    2017-06-09| PLSC| Publication of the preliminary search report|Effective date: 20170609 |
    2017-12-22| CD| Change of name or company name|Owner name: ECM TECHNOLOGIES, FR Effective date: 20171122 Owner name: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERG, FR Effective date: 20171122 |
    2017-12-29| PLFP| Fee payment|Year of fee payment: 3 |
    2019-12-31| PLFP| Fee payment|Year of fee payment: 5 |
    2020-12-28| PLFP| Fee payment|Year of fee payment: 6 |
    2021-12-31| PLFP| Fee payment|Year of fee payment: 7 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1561815A|FR3044748B1|2015-12-03|2015-12-03|COLD HOLLOW OVEN HEATED BY TWO ELECTROMAGNETIC INDUCERS, USE OF THE OVEN FOR THE FUSION OF A MIXTURE OF METALAND OXIDEREPRESENTATIVE OF A CORIUM|
    FR1561815|2015-12-03|FR1561815A| FR3044748B1|2015-12-03|2015-12-03|COLD HOLLOW OVEN HEATED BY TWO ELECTROMAGNETIC INDUCERS, USE OF THE OVEN FOR THE FUSION OF A MIXTURE OF METALAND OXIDEREPRESENTATIVE OF A CORIUM|
    KR1020187017710A| KR102047614B1|2015-12-03|2016-11-28|Use of the furnace for melting a mixture of metaland oxiderepresenting a low temperature crucible furnace, heated by two electromagnetic inductors with a device for forming a flux concentrator|
    PCT/EP2016/078955| WO2017093165A1|2015-12-03|2016-11-28|Cold crucible furnace heated by two electromagnetic inductors having a device forming a magnetic flux concentrator, use of the furnace for melting a mixture of metal and oxide representing a corium|
    CN201680080669.3A| CN108603723B|2015-12-03|2016-11-28|Cold crucible furnace with means for forming a magnetic flux concentrator heated by two electromagnetic inductors, use of the furnace for melting a mixture of metal and oxides as a melt|
    JP2018529001A| JP6807926B2|2015-12-03|2016-11-28|Use of a low temperature crucible furnace heated by two electromagnetic induction devices with a device to form a magnetic flux concentrator, a furnace for melting a mixture of metals and oxides.|
    RU2018120241A| RU2717123C2|2015-12-03|2016-11-28|Furnace with cold crucible with heating by two electromagnetic inductors equipped with device which forms magnetic flux concentrator, use of furnace for melting of mixture of metal and oxide characteristic for corium|
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